Lecture 110 of 189: Orgel Diagram: Electronic Transition and Spin (33 mins) | CUET (Common University Entrance Test) PG Chemistry (SCQP08) | Complete Video Course 189 Lectures [170 hrs : 32 mins]

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Inorganic ChemistryTransition Metals: Crystal Field Theory

Orgel diagrams

Electronic Transitions in Orgel Diagrams

  • Spin-Allowed Transitions:
  • High-Spin Consideration: The diagrams specifically illustrate high-spin states, so low-spin configurations would require Tanabe-Sugano diagrams instead.

Interpretation and Usage

  • Absorption Spectra: Orgel diagrams help predict the wavelengths of light absorbed by transition metal complexes, which correspond to the electronic transitions shown in the diagram.
  • Spectroscopic Analysis: By comparing the observed absorption spectra with the predicted transitions in the Orgel diagram, the electronic configuration and geometry of the metal complex can be inferred.
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